Diamond

Synthetics

Synthetic diamonds of various colors grown by the high-pressure high-temperature technique

Synthetic diamonds are diamonds manufactured in a laboratory, as opposed to diamonds mined from the Earth. The gemological and industrial uses of diamond have created a large demand for rough stones. This demand has been satisfied in large part by synthetic diamonds, which have been manufactured by various processes for more than half a century. However, in recent years it has become possible to produce gem-quality synthetic diamonds of significant size.
The majority of commercially available synthetic diamonds are yellow and are produced by so called High Pressure High Temperature (HPHT) processes.  The yellow color is caused by nitrogen impurities. Other colors may also be reproduced such as blue, green or pink, which are a result of the addition of boron or from irradiation after synthesis.

Colorless gem cut from diamond grown by chemical vapor deposition

Another popular method of growing synthetic diamond is chemical vapor deposition (CVD). The growth occurs under low pressure (below atmospheric pressure). It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them to chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch or laser.  This method is mostly used for coatings, but can also produce single crystals several millimeters in size (see picture).
At present, the annual production of gem quality synthetic diamonds is only a few thousand carats, whereas the total production of natural diamonds is around 120,000,000 carats (24,000 kg). Despite this fact, a purchaser is more likely to encounter a synthetic when looking for a fancy-colored diamond because nearly all synthetic diamonds are fancy-colored, while only 0.01% of natural diamonds are.

Simulants

Gem-cut synthetic silicon carbide set in a ring

A diamond simulant is defined as a non-diamond material that is used to simulate the appearance of a diamond. Diamond-simulant gems are often referred to as diamante. The most familiar diamond simulant to most consumers is cubic zirconia. The popular gemstone moissanite (silicon carbide) is often treated as a diamond simulant, although it is a gemstone in its own right. While moissanite looks similar to diamond, its main disadvantage as a diamond simulant is that cubic zirconia is far cheaper and arguably equally convincing. Both cubic zirconia and moissanite are produced synthetically.

Enhancements

Main article: Diamond enhancement

Diamond enhancements are specific treatments performed on natural or synthetic diamonds (usually those already cut and polished into a gem), which are designed to better the gemological characteristics of the stone in one or more ways. These include laser drilling to remove inclusions, application of sealants to fill cracks, treatments to improve a white diamond's color grade, and treatments to give fancy color to a white diamond.
Coatings are increasingly used to give a diamond simulant such as cubic zirconia a more "diamond-like" appearance. One such substance is diamond-like carbon—an amorphous carbonaceous material that has some physical properties similar to those of the diamond. Advertising suggests that such a coating would transfer some of these diamond-like properties to the coated stone, hence enhancing the diamond simulant. Techniques such as Raman spectroscopy should easily identify such a treatment.